EFFECTS OF FINELY DISPERSED METALLIC PALLADIUM ON MICROSTRUCTURE AND PROPERTIES OF NANOCOMPOSITES PRODUCED BY SOL-GEL TECHNIQUE

Nanosized palladium particles were incorporated into mesoporous silica matrix to obtain nanocomposites using the sol-gel technique. Effects of the finely dispersed metallic palladium on the microstructure and properties of the nanocomposites were investigated. By means of X-ray diffraction and optical absorption, it was found that palladium particles were 5-9 nm in diameter and their uniform dispersion in the mesoporous silica depended on both the content of the palladium and the structural features of the silica matrix. The results showed that the mixing method of preparation led to wider size distribution of the nanosized particles as compared to the immersion method, but dispersed degree was reduced. Although the incorporation of nanosized palladium particles could not substantially induce significant structural changes of the matrix, the apparent red-shifted optical absorptions for the nanocomposites were observed as compared to the parent monolithic silica, particularly with increase in palladium loading and calcination temperature.     

非保守圆薄板的轴对称振动和稳定性

建立了受切向均布随从力作用的圆薄板在面内周边可移、不可移两种情况下的轴对称控制方程，用打靶法直接导出求解变系数常微分方程特征值问题数值解的计算式．通过数值计算，给出了周边可移、不可移的简支、固支圆板自振频率和临界载荷的特征曲线以及相应的临界发散载荷，并分析了泊松比对圆板自振频率和临界载荷的影响．     

反射焦散线实验中斜入射光对应力强度因子测试精度的影响

本文用空间解析几何方法,推导了在一般非平行斜入射光条件下,裂纹体表面所形成的反射焦散线和初始曲线的方程.分析了倾斜入射光造成的焦散线畸变,给出了这种畸变造成的裂端应力强度因子测量误差的解析表达式.     

A critical evaluation of numerical solutions to the ‘Benchmark’ surface-flaw problem

Recent precise, elastic numerical solutions to a surface flaw in a plate under remote tension and bending have been compared to arrive at a ‘best estimate’ of the stress-intensity-factor variation along the flaw border. The geometry of the semielliptical surface flaw examined had a depth to length ratio of 0.25 (a/2c=0.25) and 25- and 75-percent relative crack depths (a/t=0.25, 0.75). The analysis methods used to determine the solutions included: Schwarz alternating technique, finite-element method and boundary-integral-equation method. The derived best-estimate curve for the stress-intensity factor is believed within 3 percent of the actual value along the crack front. The best-estimate curve compared well with scarce experimental data (±10 percent). The difference between the best-estimate curve and experiment is thought largely due to differences in geometry and Poisson's ratio.     

气缸垫对机体受力和缸套变形影响的实验研究

某四缸柴油机在试制中出现机体裂纹现象，为保证内燃机正常工作，机体裂纹问题急待处理．应用力学理论对此进行分析，得出机体裂纹是由机体受力不均匀引起的结论．同时采用实验应力分析方法，对两种四缸柴油机机体进行了对比实验研究，在实验中发现了缸垫对机体受力和缸套变形的影响，从而提出了一种有效的改进方法，使机体的应力有明显下降，并不再出现裂纹，也未出现漏油、漏气和活塞拉缸等不良现象，大大提高了产品可靠性．     

预应力钢梁体外索的张力增量分析

将预应力钢梁看作梁与索的组合结构,充分考虑了二者之间的相互作用．利用变分原理推导出在外荷载作用下,体外索张力增量的计算公式,并通过预应力钢梁模型试验对计算结果进行了验证．     

SYNTHESIS AND CHARACTERIZATION OF SURFACE-HYPERBRANCHED MAGNETITE NANOPARTICLE FOR BOVINE SERUM ALBUMIN IMMOBILIZATION

A hyperbranched polyamidoamine polymer was synthesized on the surface of magnetite nanoparticles to enhance bovine serum albumin (BSA) immobilization efficiency. The amount of immobilized bovine serum albumin (BSA) on the surface-hyperbranched magnetite nanoparticle was up to 2.5 times as much as that of magnetite nanoparticle modified with only amino silane.     

坡面流及土壤侵蚀动力学（II）——————土壤侵蚀

介绍了坡面土壤侵蚀的基本特征和主要类型, 综述了坡面土壤侵蚀动力学过程和预报模型等方面的研究进展, 包括土壤表层结皮、雨滴溅蚀、片流侵蚀、细沟侵蚀、坡面流输沙、土壤侵蚀界限坡度, 以及土壤侵蚀预报模型等. 并简要讨论了土壤侵蚀动力学研究的发展趋势.     

双周期圆截面纤维复合材料平面问题的解析法

结合双准周期Riemann边值问题理论与Eshelby等效夹杂原理，为双周期圆截面纤维复合材 料平面问题发展了一个实用有效的解析方法，获得了问题的全场级数解并与有限元结果进行 了比较. 该方法为非均匀材料的力学性质分析和复合材料等新材料的微结构设计提供了 一个有效的计算工具，也可用来评估有限元等数值与近似方法的精度.     

SURFACE MODIFICATION AND DISPERSION OF NANODIAMOND IN CLEAN OIL

The effect of different kinds of surfactants on the size distribution of nanodiamond particles in clean oil was studied.Results show that the dispersing stability of nanodiamond modified with surfactangts YS-1 and SB-18 simulta-neously is much better than those modified with either of them because of synergism of the surfactangts.And the particle size distribution in the system can be improved remarkably after the adoption of hyperdispersants such as SA-E and SA-F.Anchoring groups of those hyperdispersants can be bonded with the particle surface by chemical and/or hydrogen bonding and their soluble chains are well compatible with the dispersion media.As a result,the particles are uniformly distrbuted in the system owing to the steric stabilization.A very stable clean-oil based nanodiamond suspension with an average particle size of around 53.2 nm was prepared.